The minerals gehlenite, a calcium silico-aluminate of 2CaOAl2O3SiO2 chemical formula has been recognized as a possible marker of hydraulic limes. This statement is consistent with several thermal treatments performed on both pure chemicals and common raw materials. The physical parameters involved in the subjected treatment are 1100°C of temperature and 110 minutes in time. Pure calcium carbonate and kaolin mixes with a weight ratio ranging from 0.8 to 9.0 respectively give always a mixture of minerals with variable content of gehlenite. Its content has been found to be moderate for low and high values of the above compositional interval and elevated for the intermediate ones, with estimated values by 20 and 50 wt%, respectively. The other minerals were found to be quartz, lime, larnite, gehlenite, wollastonite, and anorthite. Rarely it has been observed the presence of mullite, and however only in samples with high content of kaolin as it happens for the mineral quartz. A roughly similar behavior has been showed from binary mixtures of common raw materials with variable content of clay and limestone.
Il minerale ghelenite, un silico alluminato di calcio dalla formula chimica bruta 2CaOAl2O3SiO2, è stato individuato come possibile marker delle calci idrauliche. Questa affermazione è derivata da una serie di trattamenti termici condotte su reagenti chimici di laboratorio e comuni materie prime. I parametri quali temperatura e tempo considerati per il trattamento termico sono rispettivamente 1100°c temperatura e 110 minuti.Miscele di carbonato di calcio e caolino ad elevato grado di purezza mescolati in rapporto ponderale primo su secondo largamente variabile nell'intervallo 0,9-8,0 originano a seguito del trattamento una miscela di minerali che contiene sempre la ghelenite. Un comportamento approssimativamente simile hanno mostarto delle miscele di materie prime a base di calcare conntenenti quantitativi variabili di argilla.
Gehlenite as mineral for binders identification / Mavilia, Letterio. - 1 con Abstracts:CD-ROM con Abstract+ lavori(2011). (Intervento presentato al convegno XIII International Cement Chemistry Congress (ICCC) tenutosi a Madrid nel 3-8 July,2011).
Gehlenite as mineral for binders identification
MAVILIA, Letterio
2011-01-01
Abstract
The minerals gehlenite, a calcium silico-aluminate of 2CaOAl2O3SiO2 chemical formula has been recognized as a possible marker of hydraulic limes. This statement is consistent with several thermal treatments performed on both pure chemicals and common raw materials. The physical parameters involved in the subjected treatment are 1100°C of temperature and 110 minutes in time. Pure calcium carbonate and kaolin mixes with a weight ratio ranging from 0.8 to 9.0 respectively give always a mixture of minerals with variable content of gehlenite. Its content has been found to be moderate for low and high values of the above compositional interval and elevated for the intermediate ones, with estimated values by 20 and 50 wt%, respectively. The other minerals were found to be quartz, lime, larnite, gehlenite, wollastonite, and anorthite. Rarely it has been observed the presence of mullite, and however only in samples with high content of kaolin as it happens for the mineral quartz. A roughly similar behavior has been showed from binary mixtures of common raw materials with variable content of clay and limestone.File | Dimensione | Formato | |
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