Catalytic behavior of supported Pd catalysts in the selective hydrogenation of campholenic aldehyde to naturanol

Neri, G.; Rizzo, G.; De Luca, L.; Donato, A.; Musolino, Maria Grazia; Pietropaolo, R.

doi:10.1007/s11144-008-5257-y

Selective catalytic reduction of campholenic aldehyde to naturanol was investigated over Sn- and Fe-doped SiO2, and Fe2O3-supported Pd catalysts. On Pd/SiO2 and Pd-Sn/SiO2 only saturated campholenic aldehyde is formed. Addition of Fe increases the C=O hydrogenation rate producing the corresponding unsaturated alcohol with a good selectivity. Also Fe2O3-supported catalysts were found to be more selective towards carbonyl hydrogenation. Addition of tin to Pd/Fe2O3 contributes to a further selectivity enhancement towards naturanol.

Titolo:	Catalytic behavior of supported Pd catalysts in the selective hydrogenation of campholenic aldehyde to naturanol
Autori:	G. NERI (Corresponding) G. RIZZO L. DE LUCA DONATO, Andrea MUSOLINO, Maria Grazia PIETROPAOLO, ROSARIO mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2008
Rivista:	REACTION KINETICS AND CATALYSIS LETTERS
Handle:	http://hdl.handle.net/20.500.12318/1223
Appare nelle tipologie:	1.1 Articolo in rivista

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http://hdl.handle.net/20.500.12318/1223

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