The adsorption of the herbicide imazamethabenz-methyl from water onto Al3+-, Fe3+-, Ca2+-, K+, and Na+-montmorillonite was studied by analytical (HPLC) methods. The adsorption from an organic solvent was also investigated by spectroscopic (IR) and X-ray diffraction measurements. It was observed that, depending on the acidic properties of the exchangeable cations, two different mechanisms may take place. The first one, acting on Fe3+- and Al3+- clays, involves the protonation of the more basic nitrogen atom of imidazolinone ring of the herbicide because of a proton transfer from the acidic metal-bound water, followed by adsorption on the clay surfaces. The second mechanism, taking place on Ca2+-, K+- and Na+-clays, is hydrogen-bond formation between the ester carbonyl group of the herbicide and hydration water metal ions and is not affected by the structure of the isomers.
Adsorption mechanisms of imazamethabenz-methyl on homoionic montmorillonite / Pusino, A; Gelsomino, Antonio; Gessa, C. - In: CLAYS AND CLAY MINERALS. - ISSN 0009-8604. - 43:3(1995), pp. 346-352. [10.1346/CCMN.1995.0430309]
Adsorption mechanisms of imazamethabenz-methyl on homoionic montmorillonite
GELSOMINO, Antonio;
1995-01-01
Abstract
The adsorption of the herbicide imazamethabenz-methyl from water onto Al3+-, Fe3+-, Ca2+-, K+, and Na+-montmorillonite was studied by analytical (HPLC) methods. The adsorption from an organic solvent was also investigated by spectroscopic (IR) and X-ray diffraction measurements. It was observed that, depending on the acidic properties of the exchangeable cations, two different mechanisms may take place. The first one, acting on Fe3+- and Al3+- clays, involves the protonation of the more basic nitrogen atom of imidazolinone ring of the herbicide because of a proton transfer from the acidic metal-bound water, followed by adsorption on the clay surfaces. The second mechanism, taking place on Ca2+-, K+- and Na+-clays, is hydrogen-bond formation between the ester carbonyl group of the herbicide and hydration water metal ions and is not affected by the structure of the isomers.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.