Hydrogenation of citral has been studied over Pt and Pt-Sn catalysts supported on activated carbon. Under the conditions used the unsaturated alcohols, geraniol and nerol, were the main reaction products. Addition of a small amount of tin (20% at.) to Pt/C increases the overall catalytic activity whereas a decrease is observed at higher tin contents. Addition of tin leads also to an increase in the selectivity to unsaturated alcohols which reaches a value of about 90%. The higher selectivity and activity are attributed to an activation of the C = O bond by tin ions.
"Selective Hydrogenation of Citral over Pt-Sn Supported on Activated Carbon / G., Neri; C., Milone; A., Donato; L., Mercadante; A. M., Visco; Donato, Andrea. - In: JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY. - ISSN 0268-2575. - 60:(1994), pp. 83-88. [10.1002/jctb.280600113]
"Selective Hydrogenation of Citral over Pt-Sn Supported on Activated Carbon
DONATO, Andrea
1994-01-01
Abstract
Hydrogenation of citral has been studied over Pt and Pt-Sn catalysts supported on activated carbon. Under the conditions used the unsaturated alcohols, geraniol and nerol, were the main reaction products. Addition of a small amount of tin (20% at.) to Pt/C increases the overall catalytic activity whereas a decrease is observed at higher tin contents. Addition of tin leads also to an increase in the selectivity to unsaturated alcohols which reaches a value of about 90%. The higher selectivity and activity are attributed to an activation of the C = O bond by tin ions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
