Recent advances in crystal engineering have shown an increasing trend in the promising employment of co-crystals obtained by benzene poly-carboxylic acids and polyamines. In this work, we present the synthesis and characterization of two “new” complexes coming from terephthalic derivates and a long chain diamine (1,10-diaminodecane). We firstly report the X-ray single crystal diffraction analysis and FT-IR results on two of these complexes. We then assign the observed experimental vibrational modes by the support of DFT analysis.

Crystal structure determination and vibrational spectroscopic studies of terephthalate and 2-amino terephthalate complexes with the 1,10-di-amonium-decane cation

MESSINA, Giacomo
2020-01-01

Abstract

Recent advances in crystal engineering have shown an increasing trend in the promising employment of co-crystals obtained by benzene poly-carboxylic acids and polyamines. In this work, we present the synthesis and characterization of two “new” complexes coming from terephthalic derivates and a long chain diamine (1,10-diaminodecane). We firstly report the X-ray single crystal diffraction analysis and FT-IR results on two of these complexes. We then assign the observed experimental vibrational modes by the support of DFT analysis.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.12318/2779
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