Recent advances in crystal engineering have shown an increasing trend in the promising employment of co-crystals obtained by benzene poly-carboxylic acids and polyamines. In this work, we present the synthesis and characterization of two “new” complexes coming from terephthalic derivates and a long chain diamine (1,10-diaminodecane). We firstly report the X-ray single crystal diffraction analysis and FT-IR results on two of these complexes. We then assign the observed experimental vibrational modes by the support of DFT analysis.
Crystal structure determination and vibrational spectroscopic studies of terephthalate and 2-amino terephthalate complexes with the 1,10-di-amonium-decane cation / Santoro, A; Bruno, G; Nicolò, F; Bella, G; Messina, Giacomo. - In: JOURNAL OF MOLECULAR STRUCTURE. - ISSN 0022-2860. - 1202:127231(2020), pp. 1-7. [10.1016/j.molstruc.2019.127231]
Crystal structure determination and vibrational spectroscopic studies of terephthalate and 2-amino terephthalate complexes with the 1,10-di-amonium-decane cation
MESSINA, Giacomo
2020-01-01
Abstract
Recent advances in crystal engineering have shown an increasing trend in the promising employment of co-crystals obtained by benzene poly-carboxylic acids and polyamines. In this work, we present the synthesis and characterization of two “new” complexes coming from terephthalic derivates and a long chain diamine (1,10-diaminodecane). We firstly report the X-ray single crystal diffraction analysis and FT-IR results on two of these complexes. We then assign the observed experimental vibrational modes by the support of DFT analysis.File | Dimensione | Formato | |
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