Hydrogenation of benzene on Rh/nylon produced cyclohexene with a high selectivity. The influence of contact time, pretreatment of catalyst and rhodium salt precursors have been studied. Samples prepared from Rh(III) were found more selective than catalysts obtained from Rh(I). It is suggested that electron deficient metal sites are responsible for cycloolefin formation.
"Rh/Nylon Catalysts for Partial Hydrogenation of Benzene to Cyclohexene" / S., Galvagno; A., Donato; G., Neri; D., Pietropaolo; P., Staiti; Donato, Andrea. - In: REACTION KINETICS AND CATALYSIS LETTERS. - ISSN 0133-1736. - 37:(1988), pp. 443-448. [10.1007/BF02062097]
"Rh/Nylon Catalysts for Partial Hydrogenation of Benzene to Cyclohexene"
DONATO, Andrea
1988-01-01
Abstract
Hydrogenation of benzene on Rh/nylon produced cyclohexene with a high selectivity. The influence of contact time, pretreatment of catalyst and rhodium salt precursors have been studied. Samples prepared from Rh(III) were found more selective than catalysts obtained from Rh(I). It is suggested that electron deficient metal sites are responsible for cycloolefin formation.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
