Selective conversion of glycerol into 1,2-propanediol in the presence of a Pd/Fe2O3 catalyst, under inert atmosphere, is reported for the first time; the hydrogen necessary for the hydrogenolysis reaction derives from the dehydrogenation of the solvent (2-propanol or ethanol), promoted by supported palladium, itself reduced “in situ” by alcohols.
Selective transfer hydrogenolysis of glycerol promoted by palladium catalysts in absence of hydrogen / Musolino, Maria Grazia; ANTONIO SCARPINO, Luciano; Mauriello, Francesco; Pietropaolo, Rosario. - In: GREEN CHEMISTRY. - ISSN 1463-9262. - 11:(2009), pp. 1511-1513. [10.1039/b915745j]
Selective transfer hydrogenolysis of glycerol promoted by palladium catalysts in absence of hydrogen
Maria Grazia MUSOLINO;FRANCESCO MAURIELLO;ROSARIO PIETROPAOLO
2009-01-01
Abstract
Selective conversion of glycerol into 1,2-propanediol in the presence of a Pd/Fe2O3 catalyst, under inert atmosphere, is reported for the first time; the hydrogen necessary for the hydrogenolysis reaction derives from the dehydrogenation of the solvent (2-propanol or ethanol), promoted by supported palladium, itself reduced “in situ” by alcohols.File in questo prodotto:
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