Selective conversion of glycerol into 1,2-propanediol in the presence of a Pd/Fe2O3 catalyst, under inert atmosphere, is reported for the first time; the hydrogen necessary for the hydrogenolysis reaction derives from the dehydrogenation of the solvent (2-propanol or ethanol), promoted by supported palladium, itself reduced “in situ” by alcohols.
Titolo: | Selective transfer hydrogenolysis of glycerol promoted by palladium catalysts in absence of hydrogen |
Autori: | PIETROPAOLO, ROSARIO (Corresponding) |
Data di pubblicazione: | 2009 |
Rivista: | |
Handle: | http://hdl.handle.net/20.500.12318/298 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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