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EnglishThe direct conversion of untreated microcrystalline cellulose into C2-C3 alcohols, through a one-pot process promoted by the heterogeneous bimetallic Pd/Fe3O4 catalyst, is presented. The process is selfsustainable without the addition of external molecular hydrogen or acid/basic promoters and is mainly selective toward ethanol. At 240 °C, a complete cellulose conversion was reached after 12 h with an ethanol molar selectivity of 51% among liquid products. The synergistic effect played by water (which aids in the chemical pretreatment means of cellulose through the hydrolysis process) and the Pd/Fe3O4 catalyst (which catalyzes the hydrogenolysis reaction driving the pattern of obtained products) is elucidated.
| Titolo: | Bioethanol Production from Unpretreated Cellulose under Neutral Selfsustainable Hydrolysis/Hydrogenolysis Conditions Promoted by the Heterogeneous Pd/Fe3O4 Catalyst | |
| Autori: | MAURIELLO, Francesco (Corresponding) | |
| Data di pubblicazione: | 2019 | |
| Rivista: | ||
| Handle: | http://hdl.handle.net/20.500.12318/3044 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Mauriello_2020_ACSOmega_Selective_editorial.pdf | Versione Editoriale (PDF) |  | Open Access Visualizza/Apri |
http://hdl.handle.net/20.500.12318/3044
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