The adsorption of the herbicides quinmerac 7-chloro-3-methylquinoline-8-carboxylic acid (QMe) and quinclorac 3,7-dichloroquinoline-8-carboxylic acid (QCI) on homoionic Fe3+-, Al3+-, Cu2+, Ca2+-, K+- and Na+-exchanged montmorillonite was studied in aqueous solution. Adsorption data were fitted to the logarithmic form of the Freundlich equation. Ca- and Na-exchanged montmorillonites were ineffective in the adsorption of QMe. On the other hand, the QMe adsorption on Fe-exchanged montmorillonite was rapid and the equilibrium was attained after 15 min. An H-type isotherm was observed for the QMe adsorption on Fe-clay, indicating a high affinity of the solute for the sorption sites and almost complete adsorption from dilute solution. On the other hand, the adsorption isotherm of QMe on Al- and K-clay was of the S-type. This shape suggests that the solvent molecules may compete for the sorption sites. A Fourier transform infrared (FTIR) study suggested that the adsorption mechanism of QMe on Fe-, Al- and K-clay involves the protonation of QMe molecule due to the acidic water surrounding the saturating cations. The greater acidity of Fe-clay compared with Al- and K-clay explains both the lower QMe adsorption observed on Al and K systems and the lack of adsorption on Na and Ca systems. In contrast, the formation of a Cu complex permitted QMe to be adsorbed to a large extent to Cu-clay as shown by FTIR analysis. The QC1 was adsorbed only by Fe-clay and the adsorption isotherm of QC1 on Fe clay was of the S-type. This finding is consistent with the lower basic character of the QC1 molecule nitrogen. In fact, the replacement of the electron-releasing methyl group in QMe with an electron-withdrawing Cl atom to form QC1 makes the nitrogen lone-pair electrons of the quinoline ring unavailable for either protonation or complexation
Adsorption of two quinolinecarboxylic acid herbicides on homoionic montmorillonites
GELSOMINO, Antonio;
2003-01-01
Abstract
The adsorption of the herbicides quinmerac 7-chloro-3-methylquinoline-8-carboxylic acid (QMe) and quinclorac 3,7-dichloroquinoline-8-carboxylic acid (QCI) on homoionic Fe3+-, Al3+-, Cu2+, Ca2+-, K+- and Na+-exchanged montmorillonite was studied in aqueous solution. Adsorption data were fitted to the logarithmic form of the Freundlich equation. Ca- and Na-exchanged montmorillonites were ineffective in the adsorption of QMe. On the other hand, the QMe adsorption on Fe-exchanged montmorillonite was rapid and the equilibrium was attained after 15 min. An H-type isotherm was observed for the QMe adsorption on Fe-clay, indicating a high affinity of the solute for the sorption sites and almost complete adsorption from dilute solution. On the other hand, the adsorption isotherm of QMe on Al- and K-clay was of the S-type. This shape suggests that the solvent molecules may compete for the sorption sites. A Fourier transform infrared (FTIR) study suggested that the adsorption mechanism of QMe on Fe-, Al- and K-clay involves the protonation of QMe molecule due to the acidic water surrounding the saturating cations. The greater acidity of Fe-clay compared with Al- and K-clay explains both the lower QMe adsorption observed on Al and K systems and the lack of adsorption on Na and Ca systems. In contrast, the formation of a Cu complex permitted QMe to be adsorbed to a large extent to Cu-clay as shown by FTIR analysis. The QC1 was adsorbed only by Fe-clay and the adsorption isotherm of QC1 on Fe clay was of the S-type. This finding is consistent with the lower basic character of the QC1 molecule nitrogen. In fact, the replacement of the electron-releasing methyl group in QMe with an electron-withdrawing Cl atom to form QC1 makes the nitrogen lone-pair electrons of the quinoline ring unavailable for either protonation or complexationI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
