The catalytic transfer hydrogenolysis of benzyl phenyl ether has been investigated using Pd/Fe3O4 as a heterogeneous catalyst and 2-propanol as a H-donor. After 90 minutes at 240 °C, the cleavage of the ether C–O bond occurs as the only reaction route without hydrogenation of the aromatic ring.
Selective arene production from transfer hydrogenolysis of benzyl phenyl ether promoted by a co-precipitated Pd/Fe3O4 catalyst / Paone, E.; Espro, C.; Pietropaolo, R.; Mauriello, F. - In: CATALYSIS SCIENCE & TECHNOLOGY. - ISSN 2044-4753. - 6:(2016), pp. 7937-7941. [10.1039/c6cy01626j]
Selective arene production from transfer hydrogenolysis of benzyl phenyl ether promoted by a co-precipitated Pd/Fe3O4 catalyst
E. Paone;R. Pietropaolo;Mauriello F
2016-01-01
Abstract
The catalytic transfer hydrogenolysis of benzyl phenyl ether has been investigated using Pd/Fe3O4 as a heterogeneous catalyst and 2-propanol as a H-donor. After 90 minutes at 240 °C, the cleavage of the ether C–O bond occurs as the only reaction route without hydrogenation of the aromatic ring.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
CST_HydroBPE.pdf
non disponibili
Licenza:
Tutti i diritti riservati (All rights reserved)
Dimensione
1.17 MB
Formato
Adobe PDF
|
1.17 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.