The kinetics of the liquid-phase hydrogenation of 4-(hydroxyamino)-2-nitrotoluene, 4-amino-2-nitrotoluene, and 2-amino-4-nitrotoluene were studied in ethanol over a 5% Pd/C catalyst, in the temperature range between 283 and 323 K and at a pressure of 0.1 MPa. The reaction rates have been described by a Langmuir - Hinshelwood type model with adsorption of the organic species and hydrogen on a different type of active site. The rate constant, the adsorption constants, and the activation energy for each reaction have been determined by a nonlinear regression analysis. The effect of molecular structure on the reactivity of mono- and dinitro derivatives has been also investigated.
Catalytic Hydrogenation of 4-(hydroxyamino)-2-nitrotoluene (4HA2NT) and 2,4-nitroaminotoluene isomers: kinetics and reactivity / Neri, G.; Musolino, Maria Grazia; Bonaccorsi, L.; Donato, A.; Mercadante, L.; Galvagno, S.. - In: INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. - ISSN 0888-5885. - 36:(1997), pp. 3619-3624. [10.1021/ie950505b]
Catalytic Hydrogenation of 4-(hydroxyamino)-2-nitrotoluene (4HA2NT) and 2,4-nitroaminotoluene isomers: kinetics and reactivity
Maria Grazia MUSOLINO;L. BONACCORSI;A. DONATO;
1997-01-01
Abstract
The kinetics of the liquid-phase hydrogenation of 4-(hydroxyamino)-2-nitrotoluene, 4-amino-2-nitrotoluene, and 2-amino-4-nitrotoluene were studied in ethanol over a 5% Pd/C catalyst, in the temperature range between 283 and 323 K and at a pressure of 0.1 MPa. The reaction rates have been described by a Langmuir - Hinshelwood type model with adsorption of the organic species and hydrogen on a different type of active site. The rate constant, the adsorption constants, and the activation energy for each reaction have been determined by a nonlinear regression analysis. The effect of molecular structure on the reactivity of mono- and dinitro derivatives has been also investigated.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
